What to Watch Tuesday: S.H.I.E.L.D. Meets Thor, Raylan Vs. Eric Roberts, Sitcom Weddings & More

JAIMIE ALEXANDEROn TV this Tuesday: Thor’s Lady Sif gives S.H.I.E.L.D. an assist, the Glee club heads to Nationals and both Brooklyn Nine-Nine and Trophy Wife are planning weddings. As a supplement to TVLine’s original features (linked within), here are 10 programs to keep on your radar.

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8 pm Glee (Fox) | New Directions heads to Los Angeles to compete in Nationals – and two special guests tag along. Marlee Matlin (Switched at Birth), Jackée Harry (Sister, Sister), Skylar Astin (Pitch Perfect) and YouTube sensation Johanna Rohrback guest-star. (Get a first look.)

8 pm Marvel’s Agents of S.H.I.E.L.D. (ABC) | Thor’s Lady Sif (Jaimie Alexander) teams up with Coulson and the team to save them from her longtime nemesis Lorelai, a deadly Asgardian seductress.

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9 pm From Dusk Till Dawn (El Rey Network) | Series premiere: Based on Robert Rodriguez’s cult classic, this 10-episode supernatural crime saga centers around Seth Gecko (D.J. Cotrona, Detroit 1-8-7) and his violent brother Richard (Zane Holtz, Make It or Break It), bank robbers wanted by the FBI and Texas Rangers Earl McGraw (Don Johnson, Nash Bridges) and Freddie Gonzalez (Jesse Garcia, Sons of Anarchy). Escaping to Mexico, the brothers run into former pastor Jacob Fuller (Robert Patrick, The X-Files) and take him and his family hostage — ultimately winding up at a vampire-filled strip club. (Click “Watch Now” to find El Rey in your nabe.)

9 pm New Girl (Fox) | Jess hires, and then must fire, Coach as the school’s new volleyball coach; Schmidt gets sued and enlists only the best Nick and Winston to represent him at the deposition.

9:30 pm Trophy Wife (ABC) | Kate plans her dream wedding after realizing she robbed herself of that special moment by eloping. Megan Mullally (Will & Grace), Dennis Haysbert (24) and Nat Faxon (Ben and Kate) guest-star.

9:30 pm Brooklyn Nine-Nine (Fox) | Charles asks Jake to be the best man at his wedding – a role complete with cake tasting and floral arrangements – while Terry, Amy and Gina support each other as they start a new extreme diet. (So… no cake for them?)

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10 pm Justified (FX) | Raylan partners jst_509_WrongRoads_0717with a maverick DEA agent (Star 80‘s Eric Roberts) whose bad behavior feels uncomfortably familiar; Boyd makes a hard choice to protect Ava.

10 pm Perception (TNT) | Pierce receives a tip that the CIA might be assassinating U.S. citizens — a conspiracy that gets even more complicated when one of his close friends is murdered.

10 pm My Big Fat Geek Wedding (Syfy) | After meeting online while playing Final Fantasy and then engaging in an eight-year courtship, Julian and Mandie are tying the knot in a medieval fantasy-style wedding – complete with a castle venue, a sword fight and elaborate props.

10:30 pm Let’s Stay Together (BET) | Time-slot premiere: In order to avoid cultural events that he hates, Charles encourages Stacy to go out with Dr. Sutton, while Jamal and Tasha try to get the twins into a prestigious preschool.

Hit the comments with your must-see picks from tonight’s lineup!